Catalytic homogeneous hydrogenation of terminal olefins by RCo(CO)2(P(OCH3)3)2 (R = CH3 or CH3C(O))

Thomas S. Janik; Michael F. Psyzczek; Jim D. Atwood

doi:10.1016/0304-5102(81)85064-X

Catalytic homogeneous hydrogenation of terminal olefins by RCo(CO)₂(P(OCH₃)₃)₂ (R = CH₃ or CH₃C(O))

Thomas S. Janik
, Michael F. Psyzczek
, Jim D. Atwood

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The complexes RCo(CO)₂L₂ (R = CH₃, CH₃C(O), L = P(OCH₃)₃) show a marked activity (450 turnovers/h) for hydrogenation of terminal olefins at ambient conditions. There is very little activity for more hindered olefins. A number of reactions have been examined, which allow a mechanism for the catalytic cycle to be presented. This mechanism involves a series of methyl → acetyl interconversion which open coordination sites, very similar to η³ · η¹ allyl interconversions.

Original language	English
Pages (from-to)	33-39
Number of pages	7
Journal	Journal of Molecular Catalysis
Volume	11
Issue number	1
DOIs	https://doi.org/10.1016/0304-5102(81)85064-X
State	Published - Apr 1981

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title = "Catalytic homogeneous hydrogenation of terminal olefins by RCo(CO)2(P(OCH3)3)2 (R = CH3 or CH3C(O))",

abstract = "The complexes RCo(CO)2L2 (R = CH3, CH3C(O), L = P(OCH3)3) show a marked activity (450 turnovers/h) for hydrogenation of terminal olefins at ambient conditions. There is very little activity for more hindered olefins. A number of reactions have been examined, which allow a mechanism for the catalytic cycle to be presented. This mechanism involves a series of methyl → acetyl interconversion which open coordination sites, very similar to η3 · η1 allyl interconversions.",

author = "Janik, \{Thomas S.\} and Psyzczek, \{Michael F.\} and Atwood, \{Jim D.\}",

year = "1981",

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doi = "10.1016/0304-5102(81)85064-X",

language = "English",

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journal = "Journal of Molecular Catalysis",

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T1 - Catalytic homogeneous hydrogenation of terminal olefins by RCo(CO)2(P(OCH3)3)2 (R = CH3 or CH3C(O))

AU - Janik, Thomas S.

AU - Psyzczek, Michael F.

AU - Atwood, Jim D.

PY - 1981/4

Y1 - 1981/4

N2 - The complexes RCo(CO)2L2 (R = CH3, CH3C(O), L = P(OCH3)3) show a marked activity (450 turnovers/h) for hydrogenation of terminal olefins at ambient conditions. There is very little activity for more hindered olefins. A number of reactions have been examined, which allow a mechanism for the catalytic cycle to be presented. This mechanism involves a series of methyl → acetyl interconversion which open coordination sites, very similar to η3 · η1 allyl interconversions.

AB - The complexes RCo(CO)2L2 (R = CH3, CH3C(O), L = P(OCH3)3) show a marked activity (450 turnovers/h) for hydrogenation of terminal olefins at ambient conditions. There is very little activity for more hindered olefins. A number of reactions have been examined, which allow a mechanism for the catalytic cycle to be presented. This mechanism involves a series of methyl → acetyl interconversion which open coordination sites, very similar to η3 · η1 allyl interconversions.

UR - https://www.scopus.com/pages/publications/0348046894

U2 - 10.1016/0304-5102(81)85064-X

DO - 10.1016/0304-5102(81)85064-X

M3 - Article

AN - SCOPUS:0348046894

SN - 0304-5102

VL - 11

SP - 33

EP - 39

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 1

ER -

Catalytic homogeneous hydrogenation of terminal olefins by RCo(CO)₂(P(OCH₃)₃)₂ (R = CH₃ or CH₃C(O))

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