Bromotricarbonyldi(Pyridine)Manganese(I)

Mario Pons; Gerhard E. Herberich; Patrick N. Kirk; Michael P. Castellani; Michael J. Rizzo; Jim D. Atwood

doi:10.1002/9781118744994.ch28

Bromotricarbonyldi(Pyridine)Manganese(I)

Mario Pons
, Gerhard E. Herberich
, Patrick N. Kirk
, Michael P. Castellani
, Michael J. Rizzo
, Jim D. Atwood

Chemistry

RWTH Aachen University
Marshall University
SUNY Buffalo

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

2 Scopus citations

Abstract

Bromotricarbonyldi(pyridine)manganese(I) was first mentioned in the early 1960s in the context of infrared studies of metal carbonyl halide complexes. Several other studies of this complex have appeared since then detailing its spectroscopic properties. More recently, this complex has been found to be a useful synthon that efficiently transfers a -Mn(CO)3 group, primarily to prepare cymantrene complexes. This chapter discusses the procedure and properties of bromotricarbonyldi(pyridine)manganese(I). Bromotricarbonyldi(pyridine)manganese(I) is an orange-red, crystalline, light-sensitive solid that is soluble in pyridine, THF, and CH2Cl2.

Original language	English
Title of host publication	Inorganic Syntheses
Publisher	Wiley-Blackwell
Pages	152-153
Number of pages	2
Volume	36
ISBN (Electronic)	9781118744994
ISBN (Print)	9781118744871
DOIs	https://doi.org/10.1002/9781118744994.ch28
State	Published - May 12 2014

Keywords

Bromotricarbonyldi(pyridine)manganese(I)
Metal carbonyl halide complexes

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10.1002/9781118744994.ch28

Cite this

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abstract = "Bromotricarbonyldi(pyridine)manganese(I) was first mentioned in the early 1960s in the context of infrared studies of metal carbonyl halide complexes. Several other studies of this complex have appeared since then detailing its spectroscopic properties. More recently, this complex has been found to be a useful synthon that efficiently transfers a -Mn(CO)3 group, primarily to prepare cymantrene complexes. This chapter discusses the procedure and properties of bromotricarbonyldi(pyridine)manganese(I). Bromotricarbonyldi(pyridine)manganese(I) is an orange-red, crystalline, light-sensitive solid that is soluble in pyridine, THF, and CH2Cl2.",

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doi = "10.1002/9781118744994.ch28",

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AU - Pons, Mario

AU - Herberich, Gerhard E.

AU - Kirk, Patrick N.

AU - Castellani, Michael P.

AU - Rizzo, Michael J.

AU - Atwood, Jim D.

PY - 2014/5/12

Y1 - 2014/5/12

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AB - Bromotricarbonyldi(pyridine)manganese(I) was first mentioned in the early 1960s in the context of infrared studies of metal carbonyl halide complexes. Several other studies of this complex have appeared since then detailing its spectroscopic properties. More recently, this complex has been found to be a useful synthon that efficiently transfers a -Mn(CO)3 group, primarily to prepare cymantrene complexes. This chapter discusses the procedure and properties of bromotricarbonyldi(pyridine)manganese(I). Bromotricarbonyldi(pyridine)manganese(I) is an orange-red, crystalline, light-sensitive solid that is soluble in pyridine, THF, and CH2Cl2.

KW - Bromotricarbonyldi(pyridine)manganese(I)

KW - Metal carbonyl halide complexes

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DO - 10.1002/9781118744994.ch28

M3 - Chapter

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SP - 152

EP - 153

BT - Inorganic Syntheses

PB - Wiley-Blackwell

ER -

Bromotricarbonyldi(Pyridine)Manganese(I)

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Keywords

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