Bimetallic Gold(I) Complexes with Ethynyl-Helicene and Bis-Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties

Monometallic gold(I)-alkynyl-helicene complexes (1 a,b) and bimetallic gold(I)-alkynyl-helicene architectures featuring the presence (2 a,b) or absence (3 a,b) of aurophilic intramolecular interactions were prepared by using different types of phosphole ligands (mono-phosphole L1 or bis-phospholes L2,3). The influence of the Au^I d¹⁰ metal center(s) on the electronic, photophysical, and chiroptical properties of these unprecedented phosphole-gold(I)-alkynyl-helicene complexes was examined. Experimental and theoretical results highlight the importance of ligand-to-ligand-type charge transfers and the strong effect of the presence or absence of Au^I-Au^I interactions in 2 a,b. Golden interactions: Monometallic and bimetallic gold(I)-alkynyl-helicene complexes featuring the presence or absence of aurophilic intramolecular interactions have been prepared by using different types of phosphole ligands (mono-phosphole or bis-phospholes). The influence of the Au^I d¹⁰ metal center(s) on the electronic, photophysical, and chiroptical properties in those novel systems has been examined (see scheme).