Assignment of the Infrared Spectrum for the Ethyl Radical

J. Pacansky; M. Dupuis

doi:10.1021/ja00366a007

Assignment of the Infrared Spectrum for the Ethyl Radical

J. Pacansky
, M. Dupuis

Department of Chemical and Biological Engineering

IBM

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

The infrared spectra of CH₃CH₂, CH₃CD₂, CD₃CH₂, and CD₃CD₂ have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.

Original language	English
Pages (from-to)	415-421
Number of pages	7
Journal	Journal of the American Chemical Society
Volume	104
Issue number	2
DOIs	https://doi.org/10.1021/ja00366a007
State	Published - 1982

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title = "Assignment of the Infrared Spectrum for the Ethyl Radical",

abstract = "The infrared spectra of CH3CH2, CH3CD2, CD3CH2, and CD3CD2 have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.",

author = "J. Pacansky and M. Dupuis",

year = "1982",

doi = "10.1021/ja00366a007",

language = "English",

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journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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T1 - Assignment of the Infrared Spectrum for the Ethyl Radical

AU - Pacansky, J.

AU - Dupuis, M.

PY - 1982

Y1 - 1982

N2 - The infrared spectra of CH3CH2, CH3CD2, CD3CH2, and CD3CD2 have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.

AB - The infrared spectra of CH3CH2, CH3CD2, CD3CH2, and CD3CD2 have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.

UR - https://www.scopus.com/pages/publications/33845554580

U2 - 10.1021/ja00366a007

DO - 10.1021/ja00366a007

M3 - Article

AN - SCOPUS:33845554580

SN - 0002-7863

VL - 104

SP - 415

EP - 421

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

ER -

Assignment of the Infrared Spectrum for the Ethyl Radical

Abstract

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