Analytical models for the design of iron-based permeable reactive barriers

The preliminary design of iron-based permeable reactive barriers is often accomplished using analytic expressions for one-dimensional groundwater flow and contaminant transport. Typically, one or more of the governing processes is simplified or neglected to facilitate development of a tractable solution. This paper presents a set of improved design equations that include the effects of dispersion, finite domain boundary, sequential decay, and production processes, and increased flow through high conductivity barriers. When applied to realistic example problems, application of the expanded design equations typically results in the specification of a larger permeable reactive barrier thickness than obtained using conventional approaches. Journal of Environmental Engineering