Amide interactions in chlorinated solvents

J. N. Spencer; S. K. Berger; C. R. Powell; B. D. Henning; G. S. Furman; W. M. Loffredo; E. M. Rydberg; R. A. Neubert; C. E. Shoop; D. N. Blauch

doi:10.1007/BF00652084

Amide interactions in chlorinated solvents

J. N. Spencer
, S. K. Berger
, C. R. Powell
, B. D. Henning
, G. S. Furman
, W. M. Loffredo
, E. M. Rydberg
, R. A. Neubert
, C. E. Shoop
, D. N. Blauch

Operations Management and Strategy

Franklin and Marshall College, Lancaster
Lebanon Valley College

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl₃), methylenechloride (CH₂Cl₂), carbontetrachloride (CCl₄), cyclohexane (C₆H₁₂), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N-H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.

Original language	English
Pages (from-to)	501-509
Number of pages	9
Journal	Journal of Solution Chemistry
Volume	10
Issue number	7
DOIs	https://doi.org/10.1007/BF00652084
State	Published - Jul 1981

Keywords

amide solvation
chlorinated hydrocarbons
cyclohexane
enthalpy of solutions
ethylacetate
N,N-dimethylformamide and N,N-dimethylacetamide
pyrrole and methylpyrrole
Transfer enthalpies

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10.1007/BF00652084

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@article{51daae82d0c84c1eab776374eda4f678,

title = "Amide interactions in chlorinated solvents",

abstract = "Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl3), methylenechloride (CH2Cl2), carbontetrachloride (CCl4), cyclohexane (C6H12), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N-H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.",

keywords = "amide solvation, chlorinated hydrocarbons, cyclohexane, enthalpy of solutions, ethylacetate, N,N-dimethylformamide and N,N-dimethylacetamide, pyrrole and methylpyrrole, Transfer enthalpies",

author = "Spencer, \{J. N.\} and Berger, \{S. K.\} and Powell, \{C. R.\} and Henning, \{B. D.\} and Furman, \{G. S.\} and Loffredo, \{W. M.\} and Rydberg, \{E. M.\} and Neubert, \{R. A.\} and Shoop, \{C. E.\} and Blauch, \{D. N.\}",

year = "1981",

month = jul,

doi = "10.1007/BF00652084",

language = "English",

volume = "10",

pages = "501--509",

journal = "Journal of Solution Chemistry",

issn = "0095-9782",

publisher = "Springer",

number = "7",

}

TY - JOUR

T1 - Amide interactions in chlorinated solvents

AU - Spencer, J. N.

AU - Berger, S. K.

AU - Powell, C. R.

AU - Henning, B. D.

AU - Furman, G. S.

AU - Loffredo, W. M.

AU - Rydberg, E. M.

AU - Neubert, R. A.

AU - Shoop, C. E.

AU - Blauch, D. N.

PY - 1981/7

Y1 - 1981/7

N2 - Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl3), methylenechloride (CH2Cl2), carbontetrachloride (CCl4), cyclohexane (C6H12), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N-H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.

AB - Enthalpies of solution and of transfer of amides for the solvents chloroform (CHCl3), methylenechloride (CH2Cl2), carbontetrachloride (CCl4), cyclohexane (C6H12), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and ethylacetate (EtOAc) have been used to isolate and quantify the solvation interactions of amides in chlorinated solvents. Specific interactions at the aminde carbonyl and N-H groups have been identified. An analysis of the transfer enthalpies of pyrrole and methylpyrrole from cyclohexane to the chlorinated solvents shows that specific interactions between the pyrroles and these solvents are similar in nature. A means of calculating differences in the transfers of different solutes between the same solvent pair is given.

KW - amide solvation

KW - chlorinated hydrocarbons

KW - cyclohexane

KW - enthalpy of solutions

KW - ethylacetate

KW - N,N-dimethylformamide and N,N-dimethylacetamide

KW - pyrrole and methylpyrrole

KW - Transfer enthalpies

UR - https://www.scopus.com/pages/publications/34250236991

U2 - 10.1007/BF00652084

DO - 10.1007/BF00652084

M3 - Article

AN - SCOPUS:34250236991

SN - 0095-9782

VL - 10

SP - 501

EP - 509

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

IS - 7

ER -

Amide interactions in chlorinated solvents

Abstract

Keywords

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