Activating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array

Son Hoang; Yanbing Guo; Andrew J. Binder; Wenxiang Tang; Sibo Wang; Jingyue (Jimmy) Liu; Tran D. Huan; Xingxu Lu; Yu Wang; Yong Ding; Eleni A. Kyriakidou; Ji Yang; Todd J. Toops; Thomas J. Pauly; Rampi Ramprasad; Pu Xian Gao

doi:10.1038/s41467-020-14816-w

Activating low-temperature diesel oxidation by single-atom Pt on TiO₂ nanowire array

Son Hoang
, Yanbing Guo
, Andrew J. Binder
, Wenxiang Tang
, Sibo Wang
, Jingyue (Jimmy) Liu
, Tran D. Huan
, Xingxu Lu
, Yu Wang
, Yong Ding
, Eleni A. Kyriakidou
, Ji Yang
, Todd J. Toops
, Thomas J. Pauly
, Rampi Ramprasad
, Pu Xian Gao

Department of Chemical and Biological Engineering

University of Connecticut
Central China Normal University
Oak Ridge National Laboratory
Arizona State University
Chinese Academy of Sciences
Georgia Institute of Technology
Umicore Autocat USA Inc.

Research output: Contribution to journal › Article › peer-review

144 Scopus citations

Abstract

Supported metal single atom catalysts (SACs) present an emerging class of low-temperature catalysts with high reactivity and selectivity, which, however, face challenges on both durability and practicality. Herein, we report a single-atom Pt catalyst that is strongly anchored on a robust nanowire forest of mesoporous rutile titania grown on the channeled walls of full-size cordierite honeycombs. This Pt SAC exhibits remarkable activity for oxidation of CO and hydrocarbons with 90% conversion at temperatures as low as ~160 ^oC under simulated diesel exhaust conditions while using 5 times less Pt-group metals than a commercial oxidation catalyst. Such an excellent low-temperature performance is sustained over hydrothermal aging and sulfation as a result of highly dispersed and isolated active single Pt ions bonded at the Ti vacancy sites with 5 or 6 oxygen ions on titania nanowire surfaces.

Original language	English
Article number	1062
Journal	Nature Communications
Volume	11
Issue number	1
DOIs	https://doi.org/10.1038/s41467-020-14816-w
State	Published - Dec 1 2020

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Hoang, S., Guo, Y., Binder, A. J., Tang, W., Wang, S., Liu, J., Huan, T. D., Lu, X., Wang, Y., Ding, Y., Kyriakidou, E. A., Yang, J., Toops, T. J., Pauly, T. J., Ramprasad, R., & Gao, P. X. (2020). Activating low-temperature diesel oxidation by single-atom Pt on TiO₂ nanowire array. Nature Communications, 11(1), Article 1062. https://doi.org/10.1038/s41467-020-14816-w

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title = "Activating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array",

abstract = "Supported metal single atom catalysts (SACs) present an emerging class of low-temperature catalysts with high reactivity and selectivity, which, however, face challenges on both durability and practicality. Herein, we report a single-atom Pt catalyst that is strongly anchored on a robust nanowire forest of mesoporous rutile titania grown on the channeled walls of full-size cordierite honeycombs. This Pt SAC exhibits remarkable activity for oxidation of CO and hydrocarbons with 90\% conversion at temperatures as low as \textasciitilde{}160 oC under simulated diesel exhaust conditions while using 5 times less Pt-group metals than a commercial oxidation catalyst. Such an excellent low-temperature performance is sustained over hydrothermal aging and sulfation as a result of highly dispersed and isolated active single Pt ions bonded at the Ti vacancy sites with 5 or 6 oxygen ions on titania nanowire surfaces.",

author = "Son Hoang and Yanbing Guo and Binder, \{Andrew J.\} and Wenxiang Tang and Sibo Wang and Liu, \{Jingyue (Jimmy)\} and Huan, \{Tran D.\} and Xingxu Lu and Yu Wang and Yong Ding and Kyriakidou, \{Eleni A.\} and Ji Yang and Toops, \{Todd J.\} and Pauly, \{Thomas J.\} and Rampi Ramprasad and Gao, \{Pu Xian\}",

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AU - Hoang, Son

AU - Guo, Yanbing

AU - Binder, Andrew J.

AU - Tang, Wenxiang

AU - Wang, Sibo

AU - Liu, Jingyue (Jimmy)

AU - Huan, Tran D.

AU - Lu, Xingxu

AU - Wang, Yu

AU - Ding, Yong

AU - Kyriakidou, Eleni A.

AU - Yang, Ji

AU - Toops, Todd J.

AU - Pauly, Thomas J.

AU - Ramprasad, Rampi

AU - Gao, Pu Xian

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N2 - Supported metal single atom catalysts (SACs) present an emerging class of low-temperature catalysts with high reactivity and selectivity, which, however, face challenges on both durability and practicality. Herein, we report a single-atom Pt catalyst that is strongly anchored on a robust nanowire forest of mesoporous rutile titania grown on the channeled walls of full-size cordierite honeycombs. This Pt SAC exhibits remarkable activity for oxidation of CO and hydrocarbons with 90% conversion at temperatures as low as ~160 oC under simulated diesel exhaust conditions while using 5 times less Pt-group metals than a commercial oxidation catalyst. Such an excellent low-temperature performance is sustained over hydrothermal aging and sulfation as a result of highly dispersed and isolated active single Pt ions bonded at the Ti vacancy sites with 5 or 6 oxygen ions on titania nanowire surfaces.

AB - Supported metal single atom catalysts (SACs) present an emerging class of low-temperature catalysts with high reactivity and selectivity, which, however, face challenges on both durability and practicality. Herein, we report a single-atom Pt catalyst that is strongly anchored on a robust nanowire forest of mesoporous rutile titania grown on the channeled walls of full-size cordierite honeycombs. This Pt SAC exhibits remarkable activity for oxidation of CO and hydrocarbons with 90% conversion at temperatures as low as ~160 oC under simulated diesel exhaust conditions while using 5 times less Pt-group metals than a commercial oxidation catalyst. Such an excellent low-temperature performance is sustained over hydrothermal aging and sulfation as a result of highly dispersed and isolated active single Pt ions bonded at the Ti vacancy sites with 5 or 6 oxygen ions on titania nanowire surfaces.

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JO - Nature Communications

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ER -

Activating low-temperature diesel oxidation by single-atom Pt on TiO₂ nanowire array

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