A theory for the kinetics of intercalation of graphite

S. H.Anderson Axdal; D. D.L. Chung

doi:10.1016/0008-6223(87)90009-1

A theory for the kinetics of intercalation of graphite

S. H.Anderson Axdal
, D. D.L. Chung

Department of Mechanical and Aerospace Engineering

Carnegie Mellon University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A theory, which takes into account the evaporation, transport and condensation of the intercalate outside the graphite and the diffusion and staging inside the graphite, is presented for the kinetics of intercalation of graphite. The theory has been applied to a number of intercalates (including Br₂, ICl, K, Rb, Cs, FeCl₃, NiCl₂, CuCl₂, PdCl₂, HNO₃, AsF₅, and SbF₅) at various temperatures. Ratecontrolling reaction steps have been identified for different types of intercalation compounds.

Original language	English
Pages (from-to)	377-389
Number of pages	13
Journal	Carbon
Volume	25
Issue number	3
DOIs	https://doi.org/10.1016/0008-6223(87)90009-1
State	Published - 1987

Keywords

Intercalation
intercalation condensation
intercalation evaporation
intercalation transportation
kinetics
staging

Access to Document

10.1016/0008-6223(87)90009-1

Cite this

@article{ea65e8845b344effbc921ddd7304cb87,

title = "A theory for the kinetics of intercalation of graphite",

abstract = "A theory, which takes into account the evaporation, transport and condensation of the intercalate outside the graphite and the diffusion and staging inside the graphite, is presented for the kinetics of intercalation of graphite. The theory has been applied to a number of intercalates (including Br2, ICl, K, Rb, Cs, FeCl3, NiCl2, CuCl2, PdCl2, HNO3, AsF5, and SbF5) at various temperatures. Ratecontrolling reaction steps have been identified for different types of intercalation compounds.",

keywords = "Intercalation, intercalation condensation, intercalation evaporation, intercalation transportation, kinetics, staging",

author = "Axdal, \{S. H.Anderson\} and Chung, \{D. D.L.\}",

year = "1987",

doi = "10.1016/0008-6223(87)90009-1",

language = "English",

volume = "25",

pages = "377--389",

journal = "Carbon",

issn = "0008-6223",

publisher = "Elsevier Ltd",

number = "3",

}

TY - JOUR

T1 - A theory for the kinetics of intercalation of graphite

AU - Axdal, S. H.Anderson

AU - Chung, D. D.L.

PY - 1987

Y1 - 1987

N2 - A theory, which takes into account the evaporation, transport and condensation of the intercalate outside the graphite and the diffusion and staging inside the graphite, is presented for the kinetics of intercalation of graphite. The theory has been applied to a number of intercalates (including Br2, ICl, K, Rb, Cs, FeCl3, NiCl2, CuCl2, PdCl2, HNO3, AsF5, and SbF5) at various temperatures. Ratecontrolling reaction steps have been identified for different types of intercalation compounds.

AB - A theory, which takes into account the evaporation, transport and condensation of the intercalate outside the graphite and the diffusion and staging inside the graphite, is presented for the kinetics of intercalation of graphite. The theory has been applied to a number of intercalates (including Br2, ICl, K, Rb, Cs, FeCl3, NiCl2, CuCl2, PdCl2, HNO3, AsF5, and SbF5) at various temperatures. Ratecontrolling reaction steps have been identified for different types of intercalation compounds.

KW - Intercalation

KW - intercalation condensation

KW - intercalation evaporation

KW - intercalation transportation

KW - kinetics

KW - staging

UR - https://www.scopus.com/pages/publications/0023223584

U2 - 10.1016/0008-6223(87)90009-1

DO - 10.1016/0008-6223(87)90009-1

M3 - Article

AN - SCOPUS:0023223584

SN - 0008-6223

VL - 25

SP - 377

EP - 389

JO - Carbon

JF - Carbon

IS - 3

ER -

A theory for the kinetics of intercalation of graphite

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this