A ring-disk study of the effect of trace chloride ion on the anodic behavior of gold in 0.2 M H2SO4

S. H. Cadle; S. Bruckenstein

doi:10.1016/S0022-0728(73)80365-1

A ring-disk study of the effect of trace chloride ion on the anodic behavior of gold in 0.2 M H₂SO₄

S. H. Cadle
, S. Bruckenstein

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The adsorption of chloride on gold electrodes in 0.2 M H₂SO₄ was studied. Chloride ion is adsorbed on gold electrodes in the potential region -0.2 V ≦E_D≦+1.8 V. Adsorbed chloride causes an increase in the amount of soluble gold produced during the anodic and cathodic parts of a potential cycle at the electrode. Isopotential points indicate that adsorbed chloride exists in two different states on a gold surface. Approximately 2.2×10^-7 M chloride is present in the supporting electrolyte as a trace impurity.

Original language	English
Pages (from-to)	325-331
Number of pages	7
Journal	Journal of Electroanalytical Chemistry
Volume	48
Issue number	3
DOIs	https://doi.org/10.1016/S0022-0728(73)80365-1
State	Published - Dec 10 1973

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title = "A ring-disk study of the effect of trace chloride ion on the anodic behavior of gold in 0.2 M H2SO4",

abstract = "The adsorption of chloride on gold electrodes in 0.2 M H2SO4 was studied. Chloride ion is adsorbed on gold electrodes in the potential region -0.2 V ≦ED≦+1.8 V. Adsorbed chloride causes an increase in the amount of soluble gold produced during the anodic and cathodic parts of a potential cycle at the electrode. Isopotential points indicate that adsorbed chloride exists in two different states on a gold surface. Approximately 2.2×10-7 M chloride is present in the supporting electrolyte as a trace impurity.",

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T1 - A ring-disk study of the effect of trace chloride ion on the anodic behavior of gold in 0.2 M H2SO4

AU - Cadle, S. H.

AU - Bruckenstein, S.

PY - 1973/12/10

Y1 - 1973/12/10

N2 - The adsorption of chloride on gold electrodes in 0.2 M H2SO4 was studied. Chloride ion is adsorbed on gold electrodes in the potential region -0.2 V ≦ED≦+1.8 V. Adsorbed chloride causes an increase in the amount of soluble gold produced during the anodic and cathodic parts of a potential cycle at the electrode. Isopotential points indicate that adsorbed chloride exists in two different states on a gold surface. Approximately 2.2×10-7 M chloride is present in the supporting electrolyte as a trace impurity.

AB - The adsorption of chloride on gold electrodes in 0.2 M H2SO4 was studied. Chloride ion is adsorbed on gold electrodes in the potential region -0.2 V ≦ED≦+1.8 V. Adsorbed chloride causes an increase in the amount of soluble gold produced during the anodic and cathodic parts of a potential cycle at the electrode. Isopotential points indicate that adsorbed chloride exists in two different states on a gold surface. Approximately 2.2×10-7 M chloride is present in the supporting electrolyte as a trace impurity.

UR - https://www.scopus.com/pages/publications/2342568793

U2 - 10.1016/S0022-0728(73)80365-1

DO - 10.1016/S0022-0728(73)80365-1

M3 - Article

AN - SCOPUS:2342568793

SN - 0022-0728

VL - 48

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JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 3

ER -

A ring-disk study of the effect of trace chloride ion on the anodic behavior of gold in 0.2 M H₂SO₄

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