A Ring-Disk Electrode Study of the Deposition and Stripping of Thin Copper Films at Platinum in Sulfuric Acid

G. W. Tindall; Stanley Bruckenstein

doi:10.1021/ac60267a014

A Ring-Disk Electrode Study of the Deposition and Stripping of Thin Copper Films at Platinum in Sulfuric Acid

G. W. Tindall
, Stanley Bruckenstein

Chemistry

University of Minnesota Twin Cities
SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The deposition and stripping of very small amounts of copper from 0.2M H₂SO₄ has been investigated. Procedures were devised for depositing a known, small amount of copper on the disk of a rotating platinum ring-disk electrode, either by constant current or constant potential electrolysis. During deposition and stripping of copper it was found that a significant amount of Cu(I) can form in 0.2M H₂SO₄ media. Quantitative agreement was found between the amount of Cu(I) and Cu(II) produced during electrochemical oxidation of a copper-plated platinum disk and the disk oxidation current. Conditions are given for the quantitative deposition and stripping of copper without interference from Cu(I) formation.

Original language	English
Pages (from-to)	1637-1640
Number of pages	4
Journal	Analytical Chemistry
Volume	40
Issue number	11
DOIs	https://doi.org/10.1021/ac60267a014
State	Published - Aug 1 1968

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title = "A Ring-Disk Electrode Study of the Deposition and Stripping of Thin Copper Films at Platinum in Sulfuric Acid",

abstract = "The deposition and stripping of very small amounts of copper from 0.2M H2SO4 has been investigated. Procedures were devised for depositing a known, small amount of copper on the disk of a rotating platinum ring-disk electrode, either by constant current or constant potential electrolysis. During deposition and stripping of copper it was found that a significant amount of Cu(I) can form in 0.2M H2SO4 media. Quantitative agreement was found between the amount of Cu(I) and Cu(II) produced during electrochemical oxidation of a copper-plated platinum disk and the disk oxidation current. Conditions are given for the quantitative deposition and stripping of copper without interference from Cu(I) formation.",

author = "Tindall, \{G. W.\} and Stanley Bruckenstein",

year = "1968",

month = aug,

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doi = "10.1021/ac60267a014",

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journal = "Analytical Chemistry",

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T1 - A Ring-Disk Electrode Study of the Deposition and Stripping of Thin Copper Films at Platinum in Sulfuric Acid

AU - Tindall, G. W.

AU - Bruckenstein, Stanley

PY - 1968/8/1

Y1 - 1968/8/1

N2 - The deposition and stripping of very small amounts of copper from 0.2M H2SO4 has been investigated. Procedures were devised for depositing a known, small amount of copper on the disk of a rotating platinum ring-disk electrode, either by constant current or constant potential electrolysis. During deposition and stripping of copper it was found that a significant amount of Cu(I) can form in 0.2M H2SO4 media. Quantitative agreement was found between the amount of Cu(I) and Cu(II) produced during electrochemical oxidation of a copper-plated platinum disk and the disk oxidation current. Conditions are given for the quantitative deposition and stripping of copper without interference from Cu(I) formation.

AB - The deposition and stripping of very small amounts of copper from 0.2M H2SO4 has been investigated. Procedures were devised for depositing a known, small amount of copper on the disk of a rotating platinum ring-disk electrode, either by constant current or constant potential electrolysis. During deposition and stripping of copper it was found that a significant amount of Cu(I) can form in 0.2M H2SO4 media. Quantitative agreement was found between the amount of Cu(I) and Cu(II) produced during electrochemical oxidation of a copper-plated platinum disk and the disk oxidation current. Conditions are given for the quantitative deposition and stripping of copper without interference from Cu(I) formation.

UR - https://www.scopus.com/pages/publications/33947303588

U2 - 10.1021/ac60267a014

DO - 10.1021/ac60267a014

M3 - Article

AN - SCOPUS:33947303588

SN - 0003-2700

VL - 40

SP - 1637

EP - 1640

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 11

ER -

A Ring-Disk Electrode Study of the Deposition and Stripping of Thin Copper Films at Platinum in Sulfuric Acid

Abstract

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