Abstract
Using a variational formulation, we show that Schrödinger's 4th-order, real-valued matter-wave equation which involves the spatial derivatives of the potential V(r), produces the precise eigenvalues of Schrödinger's 2nd-order, complex-valued matter-wave equation together with an equal number of negative, mirror eigenvalues. The variational forms of the matter-wave equations are computed numerically with a Ritz-spline method and we show how this method handles accurately discontinuous potentials with singular derivatives. Accordingly, the paper concludes that there is a real-valued description of non-relativistic quantum mechanics in association with the existence of negative, mirror energy levels. Schrödinger's classical 2nd-order, complex-valued matter-wave equation which was constructed upon factoring the 4th-order, real-valued differential operator and retaining only one of the two conjugate complex operators is a simpler description of the matter-wave, since it does not involve the derivatives of the potential V(r), at the expense of missing the negative, mirror energy levels.
| Original language | English |
|---|---|
| Article number | 100262 |
| Journal | Physics Open |
| Volume | 23 |
| DOIs | |
| State | Published - May 2025 |
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