A novel 2,18-bridged biliverdin derivative

Edward D. Sturrock; James R. Bull; Ralph E. Kirsch; Ravindra K. Pandey; Mathias O. Senge; Kevin M. Smith

doi:10.1039/C39930000872

A novel 2,18-bridged biliverdin derivative

Edward D. Sturrock
, James R. Bull
, Ralph E. Kirsch
, Ravindra K. Pandey
, Mathias O. Senge
, Kevin M. Smith

Institute for Lasers Photonics and Biophotonics

South African Medical Research Council
University of Cape Town
University of California at Davis

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and ¹H nuclear Overhauser effect studies.

Original language	English
Pages (from-to)	872-874
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39930000872
State	Published - 1993

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title = "A novel 2,18-bridged biliverdin derivative",

abstract = "Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and 1H nuclear Overhauser effect studies.",

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pages = "872--874",

journal = "Journal of the Chemical Society D: Chemical Communications",

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T1 - A novel 2,18-bridged biliverdin derivative

AU - Sturrock, Edward D.

AU - Bull, James R.

AU - Kirsch, Ralph E.

AU - Pandey, Ravindra K.

AU - Senge, Mathias O.

AU - Smith, Kevin M.

PY - 1993

Y1 - 1993

N2 - Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and 1H nuclear Overhauser effect studies.

AB - Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and 1H nuclear Overhauser effect studies.

UR - https://www.scopus.com/pages/publications/37049078134

U2 - 10.1039/C39930000872

DO - 10.1039/C39930000872

M3 - Article

AN - SCOPUS:37049078134

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SP - 872

EP - 874

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 10

ER -

A novel 2,18-bridged biliverdin derivative

Abstract

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