A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Robert G. Surbella; Lucas C. Ducati; Kristi L. Pellegrini; Bruce K. McNamara; Jochen Autschbach; Jon M. Schwantes; Christopher L. Cahill

doi:10.1039/c7cc05988d

A new Pu(III) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

Robert G. Surbella
, Lucas C. Ducati
, Kristi L. Pellegrini
, Bruce K. McNamara
, Jochen Autschbach
, Jon M. Schwantes
, Christopher L. Cahill

Chemistry

George Washington University
Universidade de São Paulo
Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Crystals of a hydrated Pu(iii) chloride, (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl₃(H₂O)₅] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

Original language	English
Pages (from-to)	10816-10819
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	78
DOIs	https://doi.org/10.1039/c7cc05988d
State	Published - 2017

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title = "A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media",

abstract = "Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.",

author = "Surbella, \{Robert G.\} and Ducati, \{Lucas C.\} and Pellegrini, \{Kristi L.\} and McNamara, \{Bruce K.\} and Jochen Autschbach and Schwantes, \{Jon M.\} and Cahill, \{Christopher L.\}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc05988d",

language = "English",

volume = "53",

pages = "10816--10819",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "78",

}

TY - JOUR

T1 - A new Pu(III) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

AU - Surbella, Robert G.

AU - Ducati, Lucas C.

AU - Pellegrini, Kristi L.

AU - McNamara, Bruce K.

AU - Autschbach, Jochen

AU - Schwantes, Jon M.

AU - Cahill, Christopher L.

PY - 2017

Y1 - 2017

N2 - Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

AB - Crystals of a hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)5] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

UR - https://www.scopus.com/pages/publications/85030312031

U2 - 10.1039/c7cc05988d

DO - 10.1039/c7cc05988d

M3 - Article

C2 - 28926048

AN - SCOPUS:85030312031

SN - 1359-7345

VL - 53

SP - 10816

EP - 10819

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

A new Pu(III) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

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