A mass spectrometric investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutral molecules

James J. Stry; James F. Garvey

doi:10.1016/0168-1176(94)04041-9

A mass spectrometric investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutral molecules

James J. Stry
, James F. Garvey

Chemistry

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

We present an investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutrals utilizing a triple quadrupole mass spectrometer. The neutral reactant gases investigated include Ar, He, N₂, CH₄, NH₃, O₂, D₂O, CH₃OH, (CH₃)₂O, C₃H₆, CH₃CH₂CHCH₂, and (CH₃)₂CH₂. We report associative additions, partial charge transfer, and the formation of various fullerene adducts. The effect of collision energy, collision cell pressure, fullerene structure, and ionization energy on the reported reactions are addressed.

Original language	English
Pages (from-to)	241-261
Number of pages	21
Journal	International Journal of Mass Spectrometry and Ion Processes
Volume	138
Issue number	C
DOIs	https://doi.org/10.1016/0168-1176(94)04041-9
State	Published - Oct 13 1994

Keywords

Cations
Fullerenes
Ion-molecule reactions
Tandem mass spectrometry

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10.1016/0168-1176(94)04041-9

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title = "A mass spectrometric investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutral molecules",

abstract = "We present an investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutrals utilizing a triple quadrupole mass spectrometer. The neutral reactant gases investigated include Ar, He, N2, CH4, NH3, O2, D2O, CH3OH, (CH3)2O, C3H6, CH3CH2CHCH2, and (CH3)2CH2. We report associative additions, partial charge transfer, and the formation of various fullerene adducts. The effect of collision energy, collision cell pressure, fullerene structure, and ionization energy on the reported reactions are addressed.",

keywords = "Cations, Fullerenes, Ion-molecule reactions, Tandem mass spectrometry",

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T1 - A mass spectrometric investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutral molecules

AU - Stry, James J.

AU - Garvey, James F.

PY - 1994/10/13

Y1 - 1994/10/13

N2 - We present an investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutrals utilizing a triple quadrupole mass spectrometer. The neutral reactant gases investigated include Ar, He, N2, CH4, NH3, O2, D2O, CH3OH, (CH3)2O, C3H6, CH3CH2CHCH2, and (CH3)2CH2. We report associative additions, partial charge transfer, and the formation of various fullerene adducts. The effect of collision energy, collision cell pressure, fullerene structure, and ionization energy on the reported reactions are addressed.

AB - We present an investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutrals utilizing a triple quadrupole mass spectrometer. The neutral reactant gases investigated include Ar, He, N2, CH4, NH3, O2, D2O, CH3OH, (CH3)2O, C3H6, CH3CH2CHCH2, and (CH3)2CH2. We report associative additions, partial charge transfer, and the formation of various fullerene adducts. The effect of collision energy, collision cell pressure, fullerene structure, and ionization energy on the reported reactions are addressed.

KW - Cations

KW - Fullerenes

KW - Ion-molecule reactions

KW - Tandem mass spectrometry

UR - https://www.scopus.com/pages/publications/0000526246

U2 - 10.1016/0168-1176(94)04041-9

DO - 10.1016/0168-1176(94)04041-9

M3 - Article

AN - SCOPUS:0000526246

SN - 0168-1176

VL - 138

SP - 241

EP - 261

JO - International Journal of Mass Spectrometry and Ion Processes

JF - International Journal of Mass Spectrometry and Ion Processes

IS - C

ER -

A mass spectrometric investigation of the gas phase ion-molecule reactions of fullerene cations and dications with various neutral molecules

Abstract

Keywords

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