A kinetic model of the first intercalation of graphite

K. K. Bardhan; D. D.L. Chung

doi:10.1016/0008-6223(80)90001-9

A kinetic model of the first intercalation of graphite

K. K. Bardhan
, D. D.L. Chung

Department of Mechanical and Aerospace Engineering

Carnegie Mellon University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A model of first rapid intercalation is presented to describe the kinetics of intercalation. The model applies to interface-controlled intercalation, as for the intercalation of Br₂ and other similar intercalates. In this model, intercalation proceeds by layer-by-layer nucleation and subsequent in-plane growth; a time gap is assumed between the nucleation of two successive intercalate layers. The model has been applied to analyze the variation of the surface and thickness profiles and mass increase during intercalation. Support of the model by relevant experimental results is discussed.

Original language	English
Pages (from-to)	303-311
Number of pages	9
Journal	Carbon
Volume	18
Issue number	5
DOIs	https://doi.org/10.1016/0008-6223(80)90001-9
State	Published - 1980

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title = "A kinetic model of the first intercalation of graphite",

abstract = "A model of first rapid intercalation is presented to describe the kinetics of intercalation. The model applies to interface-controlled intercalation, as for the intercalation of Br2 and other similar intercalates. In this model, intercalation proceeds by layer-by-layer nucleation and subsequent in-plane growth; a time gap is assumed between the nucleation of two successive intercalate layers. The model has been applied to analyze the variation of the surface and thickness profiles and mass increase during intercalation. Support of the model by relevant experimental results is discussed.",

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T1 - A kinetic model of the first intercalation of graphite

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AU - Chung, D. D.L.

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N2 - A model of first rapid intercalation is presented to describe the kinetics of intercalation. The model applies to interface-controlled intercalation, as for the intercalation of Br2 and other similar intercalates. In this model, intercalation proceeds by layer-by-layer nucleation and subsequent in-plane growth; a time gap is assumed between the nucleation of two successive intercalate layers. The model has been applied to analyze the variation of the surface and thickness profiles and mass increase during intercalation. Support of the model by relevant experimental results is discussed.

AB - A model of first rapid intercalation is presented to describe the kinetics of intercalation. The model applies to interface-controlled intercalation, as for the intercalation of Br2 and other similar intercalates. In this model, intercalation proceeds by layer-by-layer nucleation and subsequent in-plane growth; a time gap is assumed between the nucleation of two successive intercalate layers. The model has been applied to analyze the variation of the surface and thickness profiles and mass increase during intercalation. Support of the model by relevant experimental results is discussed.

UR - https://www.scopus.com/pages/publications/0019193909

U2 - 10.1016/0008-6223(80)90001-9

DO - 10.1016/0008-6223(80)90001-9

M3 - Article

AN - SCOPUS:0019193909

SN - 0008-6223

VL - 18

SP - 303

EP - 311

JO - Carbon

JF - Carbon

IS - 5

ER -

A kinetic model of the first intercalation of graphite

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