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A 3-D catalytic electrode structure for ultra-low platinum loading and high performance PEMFCs

  • Florida State University

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The microstructure of the catalyst layer in proton exchange membrane fuel cells (PEMFCs) greatly influences catalyst (Pt) utilization and cell performance. We demonstrated a 3-D catalyst electrode structure based on a double-layered carbon nanotube/nanofiber film- (buckypaper) supported Pt composite catalyst to approach an idealized microstructure. The gradient distribution of Pt, electrolyte and porosity along the thickness effectively depresses the transport resistance of proton and gas. Rated power of 1.5 W/cm2 and 0.76 W/cm2 at 0.65 V was achieved at 80°C for oxygen and air with a low Pt loading of 0.2 mg cm 2 resulting in a relatively high Pt utilization. The accelerated stress test (AST) of catalyst support showed a good durability of buckypaper support because of the high graphitization degree of carbon nanofibers.

Original languageEnglish
Title of host publicationFuel Cell Membranes, Electrode Binders, and MEA Performance
PublisherElectrochemical Society Inc.
Pages47-55
Number of pages9
Edition23
ISBN (Electronic)9781623320423
ISBN (Print)9781623320423
DOIs
StatePublished - 2012
EventSymposium on Fuel Cell Membranes, Electrode Binders, and MEA Performance - 221st ECS Meeting - Seattle, WA, United States
Duration: May 6 2012May 10 2012

Publication series

NameECS Transactions
Number23
Volume45
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

ConferenceSymposium on Fuel Cell Membranes, Electrode Binders, and MEA Performance - 221st ECS Meeting
Country/TerritoryUnited States
CitySeattle, WA
Period05/6/1205/10/12

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