4,4'-(Ethene-1,2-diyl)dipyridinium bis(2-hydroxy-3-methoxybenzoate)

Devin J. Angevine; Jason B. Benedict; W. T.A. Harrison

doi:10.1107/S2414314622005107

4,4'-(Ethene-1,2-diyl)dipyridinium bis(2-hydroxy-3-methoxybenzoate)

Devin J. Angevine
, Jason B. Benedict
, W. T.A. Harrison

Chemistry

SUNY Buffalo
University of Aberdeen

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the title double proton-transfer salt, C12H12N2 2+·2C8H7O4 -, consisting of a 1:2 ratio of 4,4'-(ethene-1,2-diyl)dipyridinium cations (trans bipyridinium ethylene) to 2-hydroxy-3-methoxybenzoate anions (o-vanillate), the complete cation is generated by crystallographic inversion symmetry and it is linked to adjacent o-vanillate anions by N - HO hydrogen bonds, forming trimolecular assemblies. The trimers are linked by C - HO hydrogen bonds as well as aromatic π-π stacking interactions into a three-dimensional network. The anion features an intramolecular O - HO hydrogen bond.

Original language	English
Article number	x220510
Journal	IUCrData
Volume	7
Issue number	Pt 5
DOIs	https://doi.org/10.1107/S2414314622005107
State	Published - May 1 2022

Keywords

bipyridine ethylene
crystal structure
organic co-crystal
vanillic acid

Access to Document

10.1107/S2414314622005107

Cite this

@article{557d9491c9f4442a9441e25c09a55da6,

title = "4,4'-(Ethene-1,2-diyl)dipyridinium bis(2-hydroxy-3-methoxybenzoate)",

abstract = "In the title double proton-transfer salt, C12H12N2 2+·2C8H7O4 -, consisting of a 1:2 ratio of 4,4'-(ethene-1,2-diyl)dipyridinium cations (trans bipyridinium ethylene) to 2-hydroxy-3-methoxybenzoate anions (o-vanillate), the complete cation is generated by crystallographic inversion symmetry and it is linked to adjacent o-vanillate anions by N - HO hydrogen bonds, forming trimolecular assemblies. The trimers are linked by C - HO hydrogen bonds as well as aromatic π-π stacking interactions into a three-dimensional network. The anion features an intramolecular O - HO hydrogen bond.",

keywords = "bipyridine ethylene, crystal structure, organic co-crystal, vanillic acid",

author = "Angevine, \{Devin J.\} and Benedict, \{Jason B.\} and Harrison, \{W. T.A.\}",

note = "Publisher Copyright: {\textcopyright} 2022 Angevine and Benedict.",

year = "2022",

month = may,

day = "1",

doi = "10.1107/S2414314622005107",

language = "English",

volume = "7",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

number = "Pt 5",

}

TY - JOUR

T1 - 4,4'-(Ethene-1,2-diyl)dipyridinium bis(2-hydroxy-3-methoxybenzoate)

AU - Angevine, Devin J.

AU - Benedict, Jason B.

AU - Harrison, W. T.A.

PY - 2022/5/1

Y1 - 2022/5/1

N2 - In the title double proton-transfer salt, C12H12N2 2+·2C8H7O4 -, consisting of a 1:2 ratio of 4,4'-(ethene-1,2-diyl)dipyridinium cations (trans bipyridinium ethylene) to 2-hydroxy-3-methoxybenzoate anions (o-vanillate), the complete cation is generated by crystallographic inversion symmetry and it is linked to adjacent o-vanillate anions by N - HO hydrogen bonds, forming trimolecular assemblies. The trimers are linked by C - HO hydrogen bonds as well as aromatic π-π stacking interactions into a three-dimensional network. The anion features an intramolecular O - HO hydrogen bond.

AB - In the title double proton-transfer salt, C12H12N2 2+·2C8H7O4 -, consisting of a 1:2 ratio of 4,4'-(ethene-1,2-diyl)dipyridinium cations (trans bipyridinium ethylene) to 2-hydroxy-3-methoxybenzoate anions (o-vanillate), the complete cation is generated by crystallographic inversion symmetry and it is linked to adjacent o-vanillate anions by N - HO hydrogen bonds, forming trimolecular assemblies. The trimers are linked by C - HO hydrogen bonds as well as aromatic π-π stacking interactions into a three-dimensional network. The anion features an intramolecular O - HO hydrogen bond.

KW - bipyridine ethylene

KW - crystal structure

KW - organic co-crystal

KW - vanillic acid

UR - https://www.scopus.com/pages/publications/85139179172

U2 - 10.1107/S2414314622005107

DO - 10.1107/S2414314622005107

M3 - Article

AN - SCOPUS:85139179172

SN - 2414-3146

VL - 7

JO - IUCrData

JF - IUCrData

IS - Pt 5

M1 - x220510

ER -

4,4'-(Ethene-1,2-diyl)dipyridinium bis(2-hydroxy-3-methoxybenzoate)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this